YuriTheHenrique Update on tests here;
I searched on the web and xdg-user-dirs man page, since the new user has it working, and man page told me that it fallback to system default configuration if it does not have a file at the login, I tried a little thing:
Got to ~/.config
and renamed user-dirs.dirs
to user-dirs.dirs.backup
, then in terminal I did xdg-user-dirs-gtk-update
and xdg-user-dirs-update
Restarted my session, and it is working.